Published April 5, 2016
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Bis[<i>S</i>-hexyl (<i>E</i>)-3-(4-methoxybenzylidene)dithiocarbazato-κ<sup>2</sup><i>N</i><sup>3</sup>,<i>S</i>]palladium(II)
- 1. University of Trieste
- 2. Shahjalal University of Science and Technology
- 3. University of Rajshahi
- 4. University of Toyama
Description
In the title complex, [Pd(C 15 H 21 N 2 OS 2 ) 2 ], the Pd II ion is located on a crystallographic inversion center. The two Schiff base ligands in a deprotonated imino thiolate form chelate the metal atom via the azomithine N and thiolate S atoms in a trans -square-planar configuration as imposed by the crystal symmetry. The complex has an approximately planar geometry with the exception of the hexyl chains; the mean plane of the five-membered chelate ring makes a dihedral angle of 15.43 (5)° with the benzene ring. In the crystal, the complex molecules are stacked along the a axis.
Translated Descriptions
⚠️
This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
في مجمع العنوان، [Pd(C 15 H 21 N 2 OS 2) 2 ]، يقع Pd II ion في مركز استثمار بلوري. تقوم الربيطتان القاعديتان لشيف في شكل إيمينو ثيولات منزوع البروتون باستخلاب ذرة المعدن عبر ذرات الآزوميثين N والثيولات S في تكوين مستوٍ عبر المربع كما يفرضه التماثل البلوري. يحتوي المجمع على هندسة مستوية تقريبًا باستثناء سلاسل الهكسيل ؛ يبلغ متوسط مستوى الحلقة الخلابية ذات الأعضاء الخمسة زاوية ثنائية السطوح تبلغ 15.43 (5)درجة مع حلقة البنزين. في البلورة، يتم تكديس الجزيئات المعقدة على طول المحور.Translated Description (English)
In the title complex, [Pd(C 15 H 21 N 2 OS 2 ) 2 ], the Pd II ion is located on a crystallographic investment center. The two Schiff base ligands in a deprotonated imino thiolate form chelate the metal atom via the azomithine N and thiolate S atoms in a trans -square-planar configuration as imposed by the crystal symmetry. The complex has an approximately planar geometry with the exception of the hexyl chains; the mean plane of the five-membered chelate ring makes a dihedral angle of 15.43 (5)° with the benzene ring. In the crystal, the complex molecules are stacked along the axis.Translated Description (French)
In the title complex, [Pd(C 15 H 21 N 2 OS 2 ) 2 ], the Pd II ion is located on a crystallographic inversion center. The two Schiff base ligands in a deprotonated imino thiolate form chelate the metal atom via the azomithine N and thiolate S atoms in a trans -square-planar configuration as imposed by the crystal symmetry. The complex has an approximately planar geometry with the exception of the hexyl chains ; the mean plane of the five-membered chelate ring makes a dihedral angle of 15.43 (5)° with the benzene ring. In the crystal, the complex molecules are stacked along the a axis.Translated Description (Spanish)
In the title complex, [Pd(C 15 H 21 N 2 OS 2 ) 2 ], the Pd II ion is located on a crystallographic inversion center. The two Schiff base ligands in a deprotonated imino thiolate form chelate the metal atom via the azomithine N and thiolate S atoms in a trans -square-planar configuration as imposed by the crystal symmetry. The complex has an approximately planar geometry with the exception of the hexyl chains; the mean plane of the five-membered chelate ring makes a dihedral angle of 15.43 (5)° with the benzene ring. In the crystal, the complex molecules are stacked along the axis.Files
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Additional details
Additional titles
- Translated title (Arabic)
- Bis[<i>S</i> - hexyl (<i>E</i> )-3 -( 4 - methoxybenzylidene)dithiocarbazate<sup>- κ 2</sup><i>N</i><sup>3</sup>,<i>S</i>]palladium(II)
- Translated title (English)
- Bis[<i>S</i>-hexyl (<i>E</i>)-3-(4-methoxybenzylidene)dithiocarbazate-κ<sup>2</sup><i>N</i><sup>3</sup>,<i>S</i>]palladium(II)
- Translated title (French)
- Bis[<i>S</i>-hexyl (<i>E</i>)-3-(4-méthoxybenzylidène)dithiocarbazato-κ<sup>2</sup><i>N</i><sup>3</sup>,<i>S</i>]palladium(II)
- Translated title (Spanish)
- Bis[<i>S</i>-hexyl (<i>E</i>)-3-(4-methoxybenzylidene)dithiocarbazato-κ<sup>2</sup><i>N</i><sup>3</sup>,<i>S</i>]palladium(II)
Identifiers
- Other
- https://openalex.org/W2329255592
- DOI
- 10.1107/s2414314616005216
References
- https://openalex.org/W1639107068
- https://openalex.org/W1972057294
- https://openalex.org/W1972221487
- https://openalex.org/W1990170643
- https://openalex.org/W2016876283
- https://openalex.org/W2031158103
- https://openalex.org/W2036282996
- https://openalex.org/W2040726624
- https://openalex.org/W2080182825
- https://openalex.org/W2131350133
- https://openalex.org/W2315391072
- https://openalex.org/W2413943381