Published April 28, 2016 | Version v1
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Chlorido{(<i>E</i>)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olato}palladium(II)

  • 1. Constantine 1 University
  • 2. Institut de Chimie de Strasbourg
  • 3. Université de Strasbourg
  • 4. Laboratoire de Chimie
  • 5. Institut de Chimie

Description

In the title complex, [Pd(C 17 H 13 N 2 O 2 )Cl], the Pd II atom is tetracoordinated by an N and two O atoms of an ( E )-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olate ligand and by a Cl atom, and has a square-planar coordination. In the crystal, molecules are linked by pairs of C—H...Cl hydrogen bonds, forming inversion dimers. The dimers are linked via offset π–π interactions [intercentroid distance = 3.546 (3) Å], forming chains running parallel to [100].

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

في مجمع العنوان، [Pd(C 17 H 13 N 2 O 2 )Cl]، يتم تنسيق ذرة Pd II بواسطة ذرات N و O من ( E )-1 -[(2 - methoxyphenyl) diazenyl] naphthalen -2 - olate ligand وبواسطة ذرة Cl، ولها تنسيق مستو مربع. في البلورة، ترتبط الجزيئات بأزواج من روابط الهيدروجين C - H...Cl، مما يشكل ثنائيات استثمارية. ترتبط الديمرات عبر تفاعلات الإزاحة π - π [المسافة بين المراكز = 3,546 (3) Å]، وتشكل سلاسل تعمل بالتوازي مع [100].

Translated Description (English)

In the title complex, [Pd(C 17 H 13 N 2 O 2 )Cl], the Pd II atom is tetracoordinated by an N and two O atoms of an ( E )-1-[(2-methoxyphenyl) diazenyl] naphthalen-2-olate ligand and by a Cl atom, and has a square-planar coordination. In the crystal, molecules are linked by pairs of C—H...Cl hydrogen bonds, forming investment dimers. The dimers are linked via offset π–π interactions [intercentroid distance = 3,546 (3) Å], forming chains running parallel to [100].

Translated Description (French)

In the title complex, [Pd(C 17 H 13 N 2 O 2 )Cl], the Pd II atom is tetracoordinated by an N and two O atoms of an ( E )-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olate ligand and by a Cl atom, and has a square-planar coordination. In the crystal, molecules are linked by pairs of C—H...Cl hydrogen bonds, forming inversion dimers. The dimers are linked via offset π–π interactions [intercentroid distance = 3.546 (3) Å], forming chains running parallel to [100].

Translated Description (Spanish)

In the title complex, [Pd(C 17 H 13 N 2 O 2 )Cl], the Pd II atom is tetracoordinated by an N and two O atoms of an ( E )-1-[(2-methoxyphenyl) diazenyl] naphthalen-2-olate ligand and by a Cl atom, and has a square-planar coordination. In the crystal, molecules are linked by pairs of C—H...Cl hydrogen bonds, forming inversion dimers. The dimers are linked via offset π–π interactions [intercentroid distance = 3.546 (3) Å], forming chains running parallel to [100].

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Additional details

Additional titles

Translated title (Arabic)
الكلوريد{(<i>E</i> )-1 -[( 2 -ميثوكسي فينيل) دايزنيل] نفثالين-2-أولاتو}بالاديوم(II)
Translated title (English)
Chloride{(<i>E</i>)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olato}palladium(II)
Translated title (French)
Chlorure{(<i>E</i>)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olato}palladium(II)
Translated title (Spanish)
Chlorido{(<i>E</i>)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olato}palladium(II)

Identifiers

Other
https://openalex.org/W2345253917
DOI
10.1107/s241431461600691x

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Algeria

References

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