Published February 23, 2013 | Version v1
Publication Open

Bis(azido-κ<i>N</i>)bis[4-(dimethylamino)pyridine-κ<i>N</i>]zinc

Description

In the title complex, [Zn(N3)2(C7H10N2)2], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl-amino)-pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra-hedral coordination geometry. In the crystal, weak C-H⋯N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol-ecules into a three-dimensional supra-molecular network.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

في مركب العنوان، [Zn(N3)2(C7H10N2)2]، يتم تنسيق ذرة Zn(II) بواسطة ذرتين N من ربيطي 4 -(ثنائي ميثيل أمينو )- بيريدين (DMAP) وبواسطة ذرتين N من أيوني أزيد في هندسة تنسيق رباعية السطوح مشوهة. في البلورة، تربط الروابط الهيدروجينية C - H N الضعيفة بين روابط DMAP و azide هذه الجزيئات المعقدة المنفصلة في شبكة فوق جزيئية ثلاثية الأبعاد.

Translated Description (English)

In the title complex, [Zn(N3)2(C7H10N2)2], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl-amino) -pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra-hedral coordination geometry. In the crystal, weak C-H N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol-ecules into a three-dimensional supra-molecular network.

Translated Description (French)

In the title complex, [Zn(N3)2(C7H10N2)2], the Zn(II) atom is coordated by two N atoms from two 4-(dimethyl-amino)-pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra-hedral coordination geometry. In the crystal, weak C-H⌘N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol-ecules into a three-dimensional supra-molecular network.

Translated Description (Spanish)

In the title complex, [Zn(N3)2(C7H10N2)2], the Zn(II) atom is coordinated by two N atoms from two 4-(dimethyl-amino) -pyridine (DMAP) ligands and by two N atoms from two azide anions in a distorted tetra-hedral coordination geometry. In the crystal, weak C-H ¦ N hydrogen bonds between the DMAP and azide ligands link these discrete complex mol-ecules into a three-dimensional supra-molecular network.

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Additional details

Additional titles

Translated title (Arabic)
Bis(azido -<i>κ N</i>)bis[4 -(dimethylamino) pyridine-<i>κ N</i>]zinc
Translated title (English)
Bis(azido-κ<i>N</i>)bis[4-(dimethylamino)pyridine-κ<i>N</i>]zinc
Translated title (French)
Bis(azido-κ<i>N</i>)bis[4-(diméthylamino)pyridine-κ<i>N</i>]zinc
Translated title (Spanish)
Bis(azido-κ<i>N</i>)bis[4-(dimetilamino)piridina-κ<i>N</i>]zinc

Identifiers

Other
https://openalex.org/W2212453018
DOI
10.1107/s1600536813004686

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Algeria

References

  • https://openalex.org/W1986834741
  • https://openalex.org/W1990170643
  • https://openalex.org/W2013890623
  • https://openalex.org/W2021720051
  • https://openalex.org/W2066370105
  • https://openalex.org/W2071170639
  • https://openalex.org/W2086945873
  • https://openalex.org/W2131350133