Published August 19, 2009 | Version v1
Publication Open

<i>trans</i>-Di-μ-iodido-bis[(3<i>H</i>-1,2-benzodithiole-3-thione)iodidomercury(II)]

Creators

  • 1. Constantine 1 University
  • 2. Laboratoire de Cristallographie, Résonance Magnétique et Modélisations
  • 3. Université de Lorraine

Description

The complete molecule of the dinuclear title compound, [Hg(2)I(4)(C(7)H(4)S(3))(2)], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each Hg(II) ion adopts a tetra-hedral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thio-carbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3)° with the DDT plane. There is no classical hydrogen bonding, but weak S⋯S inter-actions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

يتم توليد الجزيء الكامل لمركب العنوان ثنائي النواة، [Hg(2)I(4) (C(7)H(4) S (3)) (2)]، عن طريق تماثل الانقلاب البلوري. يحتوي المركب على بنية ثنائية يتبنى فيها كل أيون زئبق(II) هندسة رباعية مائية ويتم تنسيقها بواسطة ذرتين جسريتين I، أيون يوديد طرفي واحد وذرة ثيو كربونيل S واحدة (C=S) من الربيطة. يشكل المستوى المربع الذي تشكله ذرات الزئبق و I ونظيراتها المتماثلة زاوية ثنائية السطوح تبلغ 89.66 (3) درجة مع مستوى DDT. لا يوجد ترابط هيدروجيني كلاسيكي، ولكن التفاعلات Sالضعيفة من 3.4452 (7) و 3.6859 (7) Å تحافظ على تماسك البنية البلورية.

Translated Description (English)

The complete molecule of the dinuclear title compound, [Hg(2)I(4) (C(7)H(4) S (3)) (2)], is generated by crystallographic inversion symmetry. The complex has a dimeric structure in which each Hg(II) ion adopts a tetra-hydral geometry and is coordinated by two bridging I atoms, one terminal iodide ion and one thio-carbonyl S atom (C=S) of the ligand. The square plane formed by the Hg and I atoms and their symmetry counterparts makes a dihedral angle of 89.66 (3) ° with the DDT plane. There is no classical hydrogen bonding, but weak Sinter-actions of 3.4452 (7) and 3.6859 (7) Å maintain the cohesion of the crystal structure.

Translated Description (French)

La molécule complète du composé du titre dinucléaire, [Hg(2)I(4) (C(7)H(4) S (3)) (2)], est générée par symétrie d'inversion cristallographique. Le complexe a une structure dimère dans laquelle chaque ion Hg(II) adopte une géométrie tétrahydrique et est coordonné par deux atomes I de pontage, un ion iodure terminal et un atome S de thio-carbonyle (C=S) du ligand. Le plan carré formé par les atomes Hg et I et leurs homologues de symétrie fait un angle dièdre de 89,66 (3) ° avec le plan DDT. Il n'y a pas de liaison hydrogène classique, mais de faibles interactions S de 3,4452 (7) et 3,6859 (7) Å maintiennent la cohésion de la structure cristalline.

Translated Description (Spanish)

La molécula completa del compuesto del título dinuclear, [Hg(2)I(4) (C(7)H(4) S (3)) (2)], se genera por simetría de inversión cristalográfica. El complejo tiene una estructura dimérica en la que cada ion Hg(II) adopta una geometría tetrahidral y está coordinado por dos átomos de puente I, un ion yoduro terminal y un átomo de tio-carbonilo S (C=S) del ligando. El plano cuadrado formado por los átomos de Hg e I y sus contrapartes de simetría forma un ángulo diedro de 89,66 (3) ° con el plano del DDT. No hay enlaces de hidrógeno clásicos, pero las interacciones débiles de S de 3.4452 (7) y 3.6859 (7) Å mantienen la cohesión de la estructura cristalina.

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Additional details

Additional titles

Translated title (Arabic)
<i></i>trans - Diμ - iodido - bis[(3<i>H -1,2</i> - benzodithiole -3 - thione) iodidomercury (II)]
Translated title (English)
<i></i>trans-Diμ-iodido-bis [(3 H-1,2-benzodithiole-3-thione<i>)</i> iodidomercury (II)]
Translated title (French)
<i></i>trans-Diμ-iodido-bis [(3 H-1,2-benzodithiole-3-thione<i>)</i> iodidomercure (II)]
Translated title (Spanish)
<i></i>trans-Diμ-iodido-bis [(3 H-1,2-benzoditiol-3-tiona<i>)</i> iodidomercurio (II)]

Identifiers

Other
https://openalex.org/W2228684353
DOI
10.1107/s1600536809032152

Is supplement to
https://openalex.org/W4318816969 (Other)
https://openalex.org/W2300182960 (Other)
https://openalex.org/W2161756346 (Other)
https://openalex.org/W2128884622 (Other)
https://openalex.org/W2112380088 (Other)
https://openalex.org/W2079677848 (Other)
https://openalex.org/W2075921262 (Other)
https://openalex.org/W1977613337 (Other)
https://openalex.org/W1715467939 (Other)
https://openalex.org/W129000474 (Other)

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Algeria

References

  • https://openalex.org/W1997596461
  • https://openalex.org/W1999292430
  • https://openalex.org/W2044398925
  • https://openalex.org/W2044822936
  • https://openalex.org/W2059020082
  • https://openalex.org/W2063334178
  • https://openalex.org/W2080182825
  • https://openalex.org/W2131350133
  • https://openalex.org/W2319777746