Published February 25, 2009 | Version v1
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Li<sub>3</sub>Al(MoO<sub>2</sub>)<sub>2</sub>O<sub>2</sub>(AsO<sub>4</sub>)<sub>2</sub>

  • 1. Tunis University
  • 2. Tunis El Manar University

Description

Single crystals of trilithium(I) aluminium(III) bis-[dioxidomolybdenum(VI)] dioxide bis-[arsenate(V)], Li(3)AlMo(2)As(2)O(14), have been prepared by solid-state reaction at 788 K. The structure consists of AsO(4) tetra-hedra, AlO(6) octa-hedra and Mo(2)O(10) groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li(+) ions are located. This structure is compared with compounds having (MX(2)O(12))(n) chains (M = Mo, Al and X = P, As) and others containing M(2)O(10) (M = Mo, Fe) dimers.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

تم تحضير بلورات مفردة من ثلاثي ليثيوم (1) ألومنيوم(3) مكرر - [ثاني أكسيد موليبدينوم (6)] ثاني أكسيد مكرر - [زرنيخات (5)]، لي (3) ألمو (2) As (2) O(14)، بواسطة تفاعل الحالة الصلبة عند 788 كلفن. يتكون الهيكل من مجموعات AsO(4) رباعي السطوح و AlO(6) ثماني السطوح و Mo(2)O(10) تتقاسم الزوايا لتشكيل إطار ثلاثي الأبعاد يحتوي على قنوات تعمل على التوالي على طول الاتجاهين [100] و [010]، حيث توجد أيونات Li(+). تتم مقارنة هذا الهيكل مع المركبات التي تحتوي على (MX(2)O(12))(n) سلاسل (M = Mo، Al و X = P، As) وغيرها من المركبات التي تحتوي على M(2)O(10) (M = Mo، Fe) دايمرات.

Translated Description (English)

Single crystals of trilithium(I) aluminium(III) bis-[dioxidomolybdenum (VI)] dioxide bis-[arsenate (V)], Li(3) AlMo (2)As(2)O(14), have been prepared by solid-state reaction at 788 K. The structure consists of AsO(4) tetra-hedra, AlO(6) octa-hedra and Mo(2)O(10) groups sharing corners to form a three-dimensional framework containing channels running respectively along the [100] and [010] directions, where the Li(+) ions are located. This structure is compared with compounds having (MX(2)O(12))(n) chains (M = Mo, Al and X = P, As) and others containing M(2)O(10) (M = Mo, Fe) dimers.

Translated Description (French)

Des monocristaux de trilithium(I) aluminium(III) bis-[dioxydomolybdène (VI)] dioxyde de bis-[arséniate (V)], Li(3) AlMo (2)As(2)O(14), ont été préparés par réaction à l'état solide à 788 K. La structure se compose de groupes de tétraèdres AsO(4), d'octaèdres AlO(6) et de Mo(2)O(10) partageant des coins pour former un cadre tridimensionnel contenant des canaux s'étendant respectivement le long des directions [100] et [010], où les ions Li(+) sont situés. Cette structure est comparée à des composés ayant des chaînes (MX (2)O(12)) (n) (M = Mo, Al et X = P, As) et d'autres contenant des dimères M(2)O(10) (M = Mo, Fe).

Translated Description (Spanish)

Los cristales individuales de trilitio(I) aluminio(III) bis-[dioxidomolibdeno (VI)] dióxido bis-[arseniato (V)], Li(3) AlMo (2)As(2)O(14), se han preparado mediante reacción en estado sólido a 788 K. La estructura consta de grupos AsO(4) tetra-hedra, Alo(6) octa-hedra y Mo(2)O(10) que comparten esquinas para formar un marco tridimensional que contiene canales que corren respectivamente a lo largo de las direcciones [100] y [010], donde se encuentran los iones Li(+). Esta estructura se compara con compuestos que tienen cadenas (MX(2)O(12))(n) (M = Mo, Al y X = P, As) y otros que contienen dímeros de M(2)O(10) (M = Mo, Fe).

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Additional details

Additional titles

Translated title (Arabic)
Li<sub>3</sub>Al(MoO<sub>2</sub>)<sub>2</sub>O<sub>2</sub>(AsO<sub>4</sub>)<sub>2</sub>
Translated title (English)
Li<sub>3</sub>Al(MoO<sub>2</sub>)<sub>2</sub>O<sub>2</sub>(AsO<sub>4</sub>)<sub>2</sub>
Translated title (French)
Li<sub>3</sub>Al(MoO<sub>2</sub>)<sub>2</sub>O<sub>2</sub>(AsO<sub>4</sub>)<sub>2</sub>
Translated title (Spanish)
Li<sub>3</sub>Al(MoO<sub>2</sub>)<sub>2</sub>O<sub>2</sub>(AsO<sub>4</sub>)<sub>2</sub>

Identifiers

Other
https://openalex.org/W2270211233
DOI
10.1107/s160053680900631x

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Tunisia

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