Published December 18, 2010 | Version v1
Publication Open

{2-[(Benzoyloxy)methyl]-1-oxo-3<i>H</i>-pyrrolizin-2-yl}methyl benzoate

Creators

  • 1. Pakistan Council of Scientific & Industrial Research
  • 2. International Center for Chemical and Biological Sciences
  • 3. University of Karachi
  • 4. Tianjin University of Science and Technology

Description

The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis-(hy-droxy-meth-yl)-2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine·The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26 (11) and 70.75 (10)° with respect to the pyrrolizine ring system. Weak inter-molecular C-H⋯O hydrogen bonding occurs in the crystal structure.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

تم تحضير مركب العنوان، C(23)H(19)NO(5)، عن طريق استرة 2،2 - bis - (hy - droxy - methyl) -2،3 - dihydro -1H - pyrrolizin -1 - one مع كلوريد البنزويل في البيريدين · يكون نظام حلقة البيروليزين مستويًا تقريبًا مع انحراف أقصى قدره 0.008 (2) Å عن المستوى الأدنى للمربعات ؛ يتم توجيه حلقتي الفينيل بزوايا ثنائية السطوح تبلغ 64.26 (11) و 70.75 (10) درجة فيما يتعلق بنظام حلقة البيروليزين. يحدث الترابط الهيدروجيني C- HO الضعيف بين الجزيئات في البنية البلورية.

Translated Description (English)

The title compound, C(23)H(19)NO(5), was prepared by esterification of 2,2-bis- (hy-droxy-methyl) -2,3-dihydro-1H-pyrrolizin-1-one with benzoyl chloride in pyridine · The pyrrolizine ring system is approximately planar with a maximum deviation of 0.008 (2) Å from the least-squares plane; the two phenyl rings are oriented at dihedral angles of 64.26 (11) and 70.75 (10) ° with respect to the pyrrolizine ring system. Weak inter-molecularC-H O hydrogen bonding occurs in the crystal structure.

Translated Description (French)

Le composé du titre, C(23)H(19)NO(5), a été préparé par estérification de la 2,2-bis- (hy-droxy-méthyl) -2,3-dihydro-1H-pyrrolizin-1-one avec du chlorure de benzoyle dans la pyridine. Le système cyclique de la pyrrolizine est approximativement planaire avec un écart maximal de 0,008 (2) Å par rapport au plan des moindres carrés ; les deux cycles phényles sont orientés à des angles diédriques de 64,26 (11) et 70,75 (10) ° par rapport au système cyclique de la pyrrolizine. Une faible liaisonhydrogène C-HO intermoléculaire se produit dans la structure cristalline.

Translated Description (Spanish)

El compuesto del título, C(23)H(19)NO(5), se preparó por esterificación de 2,2-bis- (hy-droxy-methyl) -2,3-dihidro-1H-pirrolizin-1-ona con cloruro de benzoílo en piridina · El sistema de anillos de pirrolizina es aproximadamente plano con una desviación máxima de 0.008 (2) Å del plano de mínimos cuadrados; los dos anillos de fenilo están orientados en ángulos diedros de 64.26 (11) y 70.75 (10) ° con respecto al sistema de anillos de pirrolizina. El enlace de hidrógeno C-H O intermolecular débil ocurre en la estructura cristalina.

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Additional details

Additional titles

Translated title (Arabic)
{2-[(Benzoyloxy)methyl<i>]-1</i> - oxo -3 H - pyrrolizin -2 - yl} بنزوات الميثيل
Translated title (English)
{2-[(Benzoyloxy)methyl<i>]</i> -1-oxo-3 H-pyrrolizin-2-yl}methyl benzoate
Translated title (French)
Benzoate de {2-[(Benzoyloxy)méthyl<i>]</i> -1-oxo-3 H-pyrrolizin-2-yl}méthyle
Translated title (Spanish)
Benzoato de {2-[(benzoiloxi)metil<i>]</i> -1-oxo-3 H-pirrolizin-2-il}metilo

Identifiers

Other
https://openalex.org/W2039230129
DOI
10.1107/s1600536810051974

Is supplement to
https://openalex.org/W2952032555 (Other)
https://openalex.org/W2949301781 (Other)
https://openalex.org/W2587032915 (Other)
https://openalex.org/W2253171165 (Other)
https://openalex.org/W2121540912 (Other)
https://openalex.org/W2026228516 (Other)
https://openalex.org/W2011618143 (Other)
https://openalex.org/W1988505726 (Other)
https://openalex.org/W1978483000 (Other)
https://openalex.org/W129000474 (Other)

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Pakistan

References

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