Published November 3, 2017
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<strong>STUDY ON REACTION OF <span>SUBSTITUTED 4-METHYLQUINOLIN-2(1<em>H</em>)-ONES</span></strong><strong> WITH SODIUM AZIDE</strong>
- 1. VNU University of Science
Description
Reaction of different substituted 2-chloro-4-methylquinolines with sodium azide changed the direction to substituted tetrazolo[1,5-a]quinolines instead corresponding 2-azido-4-methylquinolines. Required 2-chloro-derivatives were obtained from substituted 4-methylquinolin-2(1H)-ones, which were synthesized by ring closing corresponding (un)substituted acetoacetanildes in the presence of ionic liquid [Bmim]OH. The structures of obtained compounds have been confirmed by using spectroscopic methods (IR, NMR and MS).
Translated Descriptions
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This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
أدى تفاعل 2 - chloro -4 - methylquinolines المستبدلة المختلفة مع أزيد الصوديوم إلى تغيير الاتجاه إلى tetrazolo [1,5 - a] quinolines المستبدلة بدلاً من 2 - azido -4 - methylquinolines المقابلة. تم الحصول على مشتقات 2 - chloro المطلوبة من 4 - methylquinolin -2 (1H) - ones المستبدلة، والتي تم تصنيعها عن طريق إغلاق الحلقة المقابلة (un) استبدال acetoacetanildes في وجود السائل الأيوني [Bmim] OH. تم تأكيد هياكل المركبات التي تم الحصول عليها باستخدام طرق مطيافية (IR، NMR و MS).Translated Description (English)
Reaction of different substituted 2-chloro-4-methylquinolines with sodium azide changed the direction to substituted tetrazolo [1,5-a]quinolines instead corresponding 2-azido-4-methylquinolines. Required 2-chloro-derivatives were obtained from substituted 4-methylquinolin-2 (1H) -ones, which were synthesized by ring closing corresponding (un) substituted acetoacetanildes in the presence of ionic liquid [Bmim] OH. The structures of obtained compounds have been confirmed by using spectroscopic methods (IR, NMR and MS).Translated Description (French)
La réaction de différentes 2-chloro-4-méthylquinoléines substituées avec l'azoture de sodium a changé la direction en tétrazolo [1,5-a]quinoléines substituées à la place des 2-azido-4-méthylquinoléines correspondantes. Les dérivés 2-chloro nécessaires ont été obtenus à partir de 4-méthylquinolin-2 (1H) -ones substituées, qui ont été synthétisées par fermeture de cycle correspondant à des acétoacétanildes (non) substituées en présence de [Bmim] OH liquide ionique. Les structures des composés obtenus ont été confirmées en utilisant des méthodes spectroscopiques (IR, RMN et SM).Translated Description (Spanish)
La reacción de diferentes 2-cloro-4-metilquinolinas sustituidas con azida de sodio cambió la dirección a tetrazol [1,5-a]quinolinas sustituidas en lugar de las 2-azido-4-metilquinolinas correspondientes. Los 2-cloro-derivados requeridos se obtuvieron a partir de 4-metilquinolin-2 (1H) -onas sustituidas, que se sintetizaron mediante el cierre del anillo de acetoacetanildes (no) sustituidos correspondientes en presencia de líquido iónico [Bmim] OH. Las estructuras de los compuestos obtenidos se han confirmado mediante el uso de métodos espectroscópicos (IR, NMR y MS).Files
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Additional details
Additional titles
- Translated title (Arabic)
- < strong > دراسة حول رد فعل < span > استبدال 4 -ميثيل كوينولين-2 (1 < em > H </ em >)- ONES </ span ></ strong >< strong > بأزيد الصوديوم </ strong >
- Translated title (English)
- < strong > study ON REACTION OF < span > substituted 4-METHYLQUINOLIN-2 (1 < em > H </em >) -ONES </span > </strong > < strong > WITH SODIUM AZIDE </strong >
- Translated title (French)
- < strong > étude sur LA RÉACTION des 4-METHYLQUINOLIN-2 (1 < em > H </em >) -ONES substituées < span > </strong > < strong > AVEC L'AZOIDE DE SODIUM </strong >
- Translated title (Spanish)
- < strong > estudio sobre LA REACCIÓN DE LA < span > 4-METILQUINOLINA-2 sustituida (1 < em > H </em >) -ONES </span > </strong > < strong > CON AZIDA DE SODIO </strong >
Identifiers
- Other
- https://openalex.org/W2770749881
- DOI
- 10.3390/ecsoc-21-04771
References
- https://openalex.org/W1825722006
- https://openalex.org/W2142169194
- https://openalex.org/W2170461998
- https://openalex.org/W4248104288