Published January 31, 2012
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Poly[[diaquatetrakis(μ<sub>2</sub>-benzene-1,4-dicarbonitrile-κ<sup>2</sup><i>N</i>:<i>N</i>′)iron(II)] bis[tetrachloridoferrate(III)] nitromethane tetrasolvate]
Description
In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra-coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol-ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4,4) square grid layers. The tetra-chloridoferrate(III) anions and nitro-methane solvent mol-ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra-molecular structure through O-H⋯Cl and O-H⋯O hydrogen bonds.
Translated Descriptions
⚠️
This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
في مركب العنوان، {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)· 4CH (3)NO(2 )}( n)، تكون أيونات Fe(II) و Fe(III) سداسية ورباعية التنسيق، على التوالي. يقع كل جزيء فريد من البنزين-1، 4 -ديكاربونيتريل مول عبر مركز انعكاس بلوري وجسور اثنين من أيونات الحديد(II) (يقع كل منهما على مركز انعكاس)، مما يولد طبقات شبكة مربعة ثنائية الأبعاد (4.4). تقع أنيوناترباعي كلوريدوفيرات (III) وحبيبات مول المذيبات نيترو ميثان بين طبقات الشبكة المربعة وترتبط أيضًا بالطبقات المجاورة في بنية فوق جزيئية ثلاثية الأبعاد من خلال روابط الهيدروجين O - H Cl و O - H O.Translated Description (English)
In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra-coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol-ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4.4) square grid layers. The tetra-chloridoferrate(III) anions and nitro-methane solvent mol-ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra-molecular structure through O-H Cl and O-H O hydrogen bonds.Translated Description (French)
In the title compound, {[Fe(II)(C(8)H(4)N(2)] (2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra-coordinated, respectively. Each unique benzène-1,4-dicarbonitrile mol-ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4,4) square grid layers. The tetra-chloridoferrate(III) anions and nitro-methane solvent mol-ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra-molecular structure through O-H⌘ Cl and O-HO hydrogen bonds.Translated Description (Spanish)
In the title compound, {[Fe(II)(C(8)H(4)N(2))(2)(H(2)O)(2)][Fe(III)Cl(4)](2)·4CH(3)NO(2)}(n), the Fe(II) and Fe(III) ions are hexa- and tetra-coordinated, respectively. Each unique benzene-1,4-dicarbonitrile mol-ecule lies across a crystallographic inversion centre and bridges two Fe(II) ions (each situated on an inversion centre), generating two-dimensional (4,4) square grid layers. The tetra-chloridoferrate(III) anions and nitro-methane solvent mol-ecules lie between the square grid layers and are further link to the adjacent layers into a three-dimensional supra-molecular structure through O-H € Cl and O-H € O hydrogen bonds.Files
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Additional details
Additional titles
- Translated title (Arabic)
- بولي[[diaquatetrakis (μ<sub>2 - benzene</sub>-1,4<sup>-</sup><i>dicarbonitrile</i> - κ 2<i> N: N</i>')iron(II)] bis[tetrachloridoferrate (III)] nitromethane tetrasolvate]
- Translated title (English)
- Poly[[diaquatetrakis(μ<sub>2</sub>-benzene-1,4-dicarbonitrile-κ<sup>2</sup><i>N</i>:<i>N</i>′)iron(II)] bis[tetrachloridoferrate(III)] nitromethane tetrasolvate]
- Translated title (French)
- Poly[[diaquatetrakis(μ<sub>2</sub>-benzène-1,4-dicarbonitrile-κ<sup>2</sup><i>N</i> :<i>N</i>′)iron(II)] bis[tétrachloridoferrate(III)] nitrométhane tétrasolvant]
- Translated title (Spanish)
- Poly[[diaquatetrakis(μ<sub>2</sub>-benceno-1,4-dicarbonitrilo-κ<sup>2</sup><i>N</i>:<i>N</i>′)iron(II)] bis[tetracloridoferrato(III)] nitromethane tetrasolvate]
Identifiers
- Other
- https://openalex.org/W1423705161
- DOI
- 10.1107/s1600536812002486
References
- https://openalex.org/W2020062026
- https://openalex.org/W2028785018
- https://openalex.org/W2031158103
- https://openalex.org/W2059020082
- https://openalex.org/W2066505265
- https://openalex.org/W2091649596
- https://openalex.org/W2096984612
- https://openalex.org/W2131350133