Published July 18, 2009 | Version v1
Publication Open

Bis(creatininium) tetrachloridocadmate(II)

Creators

  • 1. University of Skikda
  • 2. Constantine 1 University
  • 3. Institut des Sciences Chimiques de Rennes
  • 4. Centre National de la Recherche Scientifique

Description

In the title compound, (C4H8N3O)2[CdCl4], the asymmetric unit comprises two creatininium cations and one tetra­chloridocadmate anion. Cd⋯O secondary bonding links one of the two imidazole rings and the anion into ion pairs. The free and bound cations form layers between which the [CdCl4]2− anions are sandwiched. The CdII atom adopts a distorted trigonal-bipyramidal geometry in which the Cd⋯O bond is axial. Inter­molecular N—H⋯Cl hydrogen bonds form a two-dimensional network parallel to (001) which ensures the junction between creatininium cations and [CdCl4]2− anions.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

في مركب العنوان، (C4H8N3O)2[CdCl4]، تتكون الوحدة غير المتماثلة من كاتيونات الكرياتينين وأنيون رابع كلوريدوكادميت واحد. تربط رابطة ثانويةإحدى حلقتي الإيميدازول والأنيون بأزواج أيونات. تشكل الكاتيونات الحرة والمربوطة طبقات تقع بين [CdCl4]2- anions. تتبنى ذرة CdII هندسة مثلثية ثنائية الهرمية مشوهة تكون فيها رابطة CdO محورية. تشكل روابط هيدروجين Cl شبكة ثنائية الأبعاد موازية لـ (001) والتي تضمن التقاطع بين كاتيونات الكرياتينيوم و [CdCl4]2- أنيونات.

Translated Description (English)

In the title compound, (C4H8N3O)2[CdCl4], the asymmetric unit comprises two creatininium cations and one tetra-chloridocadmate anion. A secondary bonding links one of the two imidazole rings and the anion into ion pairs. The free and bound cations form layers between which the [CdCl4]2− anions are sandwiched. The CdII atom adopts a distorted trigonal-bipyramidal geometry in which the CdO bond is axial. Cl hydrogen bonds form a two-dimensional network parallel to (001) which ensures the junction between creatininium cations and [CdCl4]2− anions.

Translated Description (French)

Dans le composé du titre, (C4H8N3O)2[CdCl4], l'unité asymétrique comprend deux cations créatininium et un anion tétra-chloridocadmate. Une liaison secondaire lie l'un des deux cycles imidazole et l'anion en paires d'ions. Les cations libres et liés forment des couches entre lesquelles les anions [CdCl4]2− sont pris en sandwich. L'atome CdII adopte une géométrie trigonale-bipyramidale déformée dans laquelle la liaison CdO est axiale. Les liaisons hydrogène Cl forment un réseau bidimensionnel parallèle à (001) qui assure la jonction entre les cations créatininium et les anions [CdCl4]2−.

Translated Description (Spanish)

En el compuesto del título, (C4H8N3O)2[CdCl4], la unidad asimétrica comprende dos cationes de creatininio y un anión tetra-cloridocadmato. Un enlace secundario une uno de los dos anillos de imidazol y el anión en pares iónicos. Los cationes libres y unidos forman capas entre las que se intercalan los aniones [CdCl4]2−. El átomo de CdII adopta una geometría trigonal-bipiramidal distorsionada en la que el enlace CdO es axial. Los enlaces de hidrógeno de Cl forman una red bidimensional paralela a (001) que asegura la unión entre los cationes de creatininio y los aniones [CdCl4]2−.

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Additional details

Additional titles

Translated title (Arabic)
BIS(كرياتينينيوم) رباعي كلوريدوكادميت(II)
Translated title (English)
Bis(creatininium) tetrachloridocadmate(II)
Translated title (French)
Tétrachloridocadmate de bis(créatininium)(II)
Translated title (Spanish)
Bis(creatininio) tetracloridocadmato(II)

Identifiers

Other
https://openalex.org/W1134290642
DOI
10.1107/s1600536809026944

Is supplement to
https://openalex.org/W4246755741 (Other)
https://openalex.org/W3144613255 (Other)
https://openalex.org/W2950370291 (Other)
https://openalex.org/W2779056264 (Other)
https://openalex.org/W2345369776 (Other)
https://openalex.org/W2171516250 (Other)
https://openalex.org/W2076418881 (Other)
https://openalex.org/W2072649844 (Other)
https://openalex.org/W2037202901 (Other)
https://openalex.org/W114486203 (Other)

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Algeria

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