Published March 3, 2012
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Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup><i>N</i><sup>2</sup>,<i>N</i><sup>3</sup>](trifluoromethanesulfonato-κ<i>O</i>)copper(II) trifluoromethanesulfonate
Creators
- 1. Chouaib Doukkali University
- 2. Unité de catalyse et de chimie du solide de Lille
- 3. École Nationale Supérieure de Chimie de Lille
- 4. Catalyse
- 5. Centre National de la Recherche Scientifique
- 6. Université Lille Nord de France
- 7. Mohammed V University
Description
2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L ) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF 3 O 3 S)(C 12 H 8 N 4 S) 2 (H 2 O)](CF 3 O 3 S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligands, one water molecule and one trifluoromethanesulfonate anion. The second trifluoromethanesulfonate anion does not coordinate the copper(II) cation. Each thiadiazole ligand uses one pyridyl and one thiadiazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thiadiazole ring as the S atom. The trifluoromethanesulfonate ions are involved in a three-dimensional network of O—H...O hydrogen bonds. C—H...N interactions also occur.
Translated Descriptions
⚠️
This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
2،5 - Bis (pyridin -2 - yl) -1،3،4 - thiadiazole (المشار إليه L ) وجد أنه يعمل كرباط ثنائي في مجمع العنوان الأحادي، [Cu(CF 3 O 3 S)(C 12 H 8 N 4 S) 2 (H 2 O)](CF 3 O 3 S). يُظهر المركب كاتيون نحاس(II) مشوه ثماني السطوح مرتبط برابطين ثياديازول وجزيء ماء واحد وأنيون ثلاثي فلورو ميثان سلفونات. لا ينسق الأيون الثاني ثلاثي فلورو ميثان سلفونات الكاتيون النحاسي(II). يستخدم كل ليجند ثياديازول بيريديل واحد وذرة ثياديازول N واحدة لتنسيق النحاس. تم العثور على ذرة N من بديل البيريديل الثاني غير المنسق على نفس الجانب من الحلقة 1،3،4 -ثياديازول مثل ذرة S. وتشارك أيونات ثلاثي فلورو ميثان سلفونات في شبكة ثلاثية الأبعاد من روابط الهيدروجين O - H...O. تحدث تفاعلات C - H...N أيضًا.Translated Description (English)
2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L ) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF 3 O 3 S)(C 12 H 8 N 4 S) 2 (H 2 O)](CF 3 O 3 S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligands, one water molecule and one trifluoromethanesulfonate anion. The second trifluoromethanesulfonate anion does not coordinate the copper(II) cation. Each thiadiazole ligand uses one pyridyl and one thiadiazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thiadiazole ring as the S atom. The trifluoromethanesulfonate ions are involved in a three-dimensional network of O—H...O hydrogen bonds. C—H...N interactions also occur.Translated Description (French)
2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L ) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF 3 O 3 S)(C 12 H 8 N 4 S) 2 (H 2 O)](CF 3 O 3 S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligands, one water molecule and one trifluoromethanesulfonate anion. The second trifluoromethanesulfonate anion does not coordinate the copper(II) cation. Each thiadiazole ligand uses one pyridyl and one thiadiazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thiadiazole ring as the S atom. The trifluoromethanesulfonate ions are involved in a three-dimensional network of O—H...O hydrogen bonds. C—H...N interactions also occur.Translated Description (Spanish)
2,5-Bis(pyridin-2-yl)-1,3,4-thiadiazole (denoted L ) has been found to act as a bidentate ligand in the monomeric title complex, [Cu(CF 3 O 3 S)(C 12 H 8 N 4 S) 2 (H 2 O)](CF 3 O 3 S). The complex shows a distorted octahedrally coordinated copper(II) cation which is linked to two thiadiazole ligands, one water molecule and one trifluoromethanesulfonate anion. The second trifluoromethanesulfonate anion does not coordinate the copper(II) cation. Each thiadiazole ligand uses one pyridyl and one thiadiazole N atom for the coordination of copper. The N atom of the second non-coordinating pyridyl substituent is found on the same side of the 1,3,4-thiadiazole ring as the S atom. The trifluoromethanesulfonate ions are involved in a three-dimensional network of O—H...O hydrogen bonds. C—H...N interactions also occur.Files
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Additional details
Additional titles
- Translated title (Arabic)
- ماء[2,5 -bis (pyridin<sup> -2 - yl )-1,3,4 -</sup><i>thiadiazole - κ 2 N</i><sup>2</sup>,<i>N</i><sup>3</sup> ]( trifluoromethanesulfonate - κ<i> O</i>)نحاس(II) trifluoromethanesulfonate
- Translated title (English)
- Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup><i>N</i><sup>2</sup>,<i>N</i><sup>3</sup>](trifluoromethanesulfonate-κ<i>O</i>)copper(II) trifluoromethanesulfonate
- Translated title (French)
- Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup><i>N</i><sup>2</sup>,<i>N</i><sup>3</sup>](trifluorométhanesulfonate-κ<i>O</i>)copper(II) trifluorométhanesulfonate
- Translated title (Spanish)
- Aquabis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ<sup>2</sup><i>N</i><sup>2</sup>,<i>N</i><sup>3</sup>](trifluoromethanesulfonato-κ<i>O</i>)copper(II) trifluoromethanesulfonate
Identifiers
- Other
- https://openalex.org/W2098824657
- DOI
- 10.1107/s1600536812008732
References
- https://openalex.org/W2049921781
- https://openalex.org/W2050749859
- https://openalex.org/W2059020082
- https://openalex.org/W2063334178
- https://openalex.org/W2083347083
- https://openalex.org/W2128265221
- https://openalex.org/W2131350133
- https://openalex.org/W2137896668
- https://openalex.org/W2147822162
- https://openalex.org/W2797940833