Published April 13, 2011
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(2<i>E</i>,25<i>E</i>)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0<sup>5,10</sup>.0<sup>18,23</sup>.0<sup>27,32</sup>]heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione
- 1. Hanoi National University of Education
- 2. Peoples' Friendship University of Russia
- 3. A. N. Nesmeyanov Institute of Organoelement Compounds
Description
The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis-(2-acetyl-phen-oxy)-3-oxapentane with bis-(2-formyl-phen-oxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethyl-ene fragments have E configurations. The volume of the inter-nal cavity of the macrocycle is approximately 125 Å(3). In the crystal, the mol-ecules are arranged at van der Waals distances.
Translated Descriptions
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This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
المركب الرئيسي، C(40)H (40) O(9)، هو نتاج التكثيف الكرونيكي المزدوج لـ bis -( 2 - acetyl - phen - oxy )-3 - oxapentane مع bis-( 2 - formyl - phen - oxy )-3,6 - dioxaoctane. يتضمن جزيء العنوان الكبير وحدة الهيكل العظمي 31 - crown -7 - ether ويعتمد شكلًا يشبه السرج. تحتوي شظايا الإيثيلين على تكوينات E. يبلغ حجم التجويف بين الشرجين للدراجة الكبيرة حوالي 125 Å(3). في البلورة، يتم ترتيب جزيئات المول على مسافات فان دير فالس.Translated Description (English)
The title compound, C(40)H(40)O(9), is a product of the double crotonic condensation of bis-(2-acetyl-phen-oxy)-3-oxapentane with bis-(2-formyl-phen-oxy)-3,6-dioxaoctane. The title macromolecule includes the 31-crown-7-ether skeletal unit and adopts a saddle-like conformation. The two ethyl-ene fragments have E configurations. The volume of the inter-nal cavity of the macrocycle is approximately 125 Å(3). In the crystal, the mol-ecules are arranged at van der Waals distances.Translated Description (French)
Le composé du titre, C(40)H(40)O(9), est un produit de la double condensation crotonique du bis-(2-acétyl-phén-oxy)-3-oxapentane avec le bis-(2-formyl-phén-oxy)-3,6-dioxaoctane. La macromolécule du titre comprend l'unité squelettique 31-couronne-7-éther et adopte une conformation en forme de selle. Les deux fragments éthylène ont des configurations E. Le volume de la cavité inter-nale du macrocycle est d'environ 125 Å(3). Dans le cristal, les mol-écules sont disposées à des distances de van der Waals.Translated Description (Spanish)
El compuesto del título, C(40)H(40)O(9), es un producto de la condensación crotónica doble de bis-(2-acetil-fen-oxi)-3-oxapentano con bis-(2-formil-fen-oxi)-3,6-dioxaoctano. La macromolécula del título incluye la unidad esquelética 31-corona-7-éter y adopta una conformación similar a una silla de montar. Los dos fragmentos de etileno tienen configuraciones E. El volumen de la cavidad interna del macrociclo es de aproximadamente 125 Å(3). En el cristal, las mol-éculas están dispuestas a distancias de van der Waals.Files
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Additional details
Additional titles
- Translated title (Arabic)
- (2<i>E</i>,25<i>E</i>) -11,14,17,33,36,39,42 - Heptaoxapentacyclo[41.4.0.0<sup>5,10.0 18,23.0</sup>27,32<sup>]</sup>heptatetrachonta<sup></sup> -1 (43),2,5 (10),6,8,18,20,22,25,27,29,31,44,46 - tetradecaene -4,24 - dione
- Translated title (English)
- (2<i>E</i>,25<i>E</i>)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0<sup>5,10</sup>.0<sup>18,23</sup>.0<sup>27,32</sup>]heptatetrachonta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaene-4,24-dione
- Translated title (French)
- (2<i>E</i>,25<i>E</i>)-11,14,17,33,36,39,42-Heptaoxapentacyclo[41.4.0.0<sup>5,10</sup>.0<sup>18,23</sup>.0<sup>27,32</sup>]heptatétrachonta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tétradécaène-4,24-dione
- Translated title (Spanish)
- (<i>2E ,25E</i>)<i> -11,14,17,33,36,39,42-Heptaoxapentaciclo</i> [41.4.0.0<sup> 5,10</sup>.0<sup>18,23</sup>.0<sup>27,32</sup>] heptatetraconta-1(43),2,5(10),6,8,18,20,22,25,27,29,31,44,46-tetradecaeno-4,24-diona
Identifiers
- Other
- https://openalex.org/W11947021
- DOI
- 10.1107/s1600536811013201
References
- https://openalex.org/W2011615448
- https://openalex.org/W2099677859
- https://openalex.org/W2131350133
- https://openalex.org/W2949636013
- https://openalex.org/W2951210176
- https://openalex.org/W2953008624