Published August 27, 2011 | Version v1
Publication Open

(<i>E</i>)-1-(4-Chlorobenzylidene)-2-phenylhydrazine

  • 1. University of Sargodha
  • 2. University of Faisalabad

Description

The asymmetric unit of the title compound, C13H11ClN2, contains two geometrically distinct mol­ecules; one mol­ecule is close to planar [dihedral angle between the aromatic rings = 2.44 (18)°] and the other is twisted about the linking hydrazide group [dihedral angle = 14.08 (19)°]. In the crystal, the N—H groups do not form hydrogen bonds and the mol­ecules are linked by weak C—H⋯π inter­actions.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

تحتوي الوحدة غير المتماثلة لمركب العنوان، C13H11ClN2، على جزيئين متميزين هندسيًا ؛ أحدهما قريب من المستوى [الزاوية ثنائية السطوح بين الحلقات العطرية = 2.44 (18) درجة] والآخر ملتوي حول مجموعة الهيدرازيد الرابطة [الزاوية ثنائية السطوح = 14.08 (19) درجة]. في البلورة، لا تشكل مجموعات N - H روابط هيدروجينية وترتبط الجزيئات بتفاعلات C-H π ضعيفة.

Translated Description (English)

The asymmetric unit of the title compound, C13H11ClN2, contains two geometrically distinct molecules; one molecule is close to planar [dihedral angle between the aromatic rings = 2.44 (18) °] and the other is twisted about the linking hydrazide group [dihedral angle = 14.08 (19) °]. In the crystal, the N-H groups do not form hydrogen bonds and the molecules are linked by weak C-H ̄ π inter-actions.

Translated Description (French)

L'unité asymétrique du composé du titre, C13H11ClN2, contient deux molécules géométriquement distinctes ; une molécule est proche du planaire [angle dièdre entre les cycles aromatiques = 2,44 (18) °] et l'autre est torsadée autour du groupe hydrazide de liaison [angle dièdre = 14,08 (19) °]. Dans le cristal, les groupes N-H ne forment pas de liaisons hydrogène et les molécules sont liées par de faibles interactions C-Hπ.

Translated Description (Spanish)

La unidad asimétrica del compuesto del título, C13H11ClN2, contiene dos moléculas geométricamente distintas; una molécula está cerca de ser plana [ángulo diedro entre los anillos aromáticos = 2,44 (18) °] y la otra está torcida alrededor del grupo hidrazida de enlace [ángulo diedro = 14,08 (19) °]. En el cristal, los grupos N-H no forman enlaces de hidrógeno y las moléculas están unidas por interacciones débiles C-Hπ.

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Additional details

Additional titles

Translated title (Arabic)
(<i>E</i>)-1-( 4-كلوروبنزيليدين )-2-فينيل هيدرازين
Translated title (English)
(<i>E</i>) -1-(4-Chlorobenzylidene) -2-phenylhydrazine
Translated title (French)
(<i>E</i>) -1-(4-Chlorobenzylidène) -2-phénylhydrazine
Translated title (Spanish)
(<i>E</i>) -1-(4-Clorobenciliden) -2-fenilhidracina

Identifiers

Other
https://openalex.org/W1469656534
DOI
10.1107/s1600536811032958

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Pakistan

References

  • https://openalex.org/W2049093509
  • https://openalex.org/W2059020082
  • https://openalex.org/W2063334178
  • https://openalex.org/W2128179591
  • https://openalex.org/W2131350133
  • https://openalex.org/W2145538332
  • https://openalex.org/W285707021
  • https://openalex.org/W85784825