Published April 13, 2012
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<i>catena</i>-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1<i>H</i>-1,2,4-triazole-5(4<i>H</i>)-thione-κ<sup>2</sup><i>S</i>:<i>S</i>]]
- 1. Prince of Songkla University
- 2. University of Bristol
Description
In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H⋯N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-H⋯Br inter-actions also occur.
Translated Descriptions
⚠️
This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
في بوليمر تنسيق العنوان، [CuBr (C(3)H (5) N (3) S)] (n)، تتبنى ذرة Cu(I) هندسة تنسيق رباعية الكثافة CuS (2)Br(2) الناشئة عن اثنين من 4 - methyl -1H -1,2,4 - triazole -3 (4H) - thione ligands واثنين من أيونات البروميد. تعمل كل من ذرات S و Br كروابط جسرية، وتربط أزواج ذرات Cu(I) وتولد سلاسل تنتشر في [100]. تولد الروابط الهيدروجينية N - H - N بين السلاسل طبقات في مستوى التيار المتردد. تحدث أيضًا تفاعلات N - H Br ضعيفة داخل السلسلة.Translated Description (English)
In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3 (4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-H Br inter-actions also occur.Translated Description (French)
In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3(4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H⌘N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-H⌘Br inter-actions also occur.Translated Description (Spanish)
In the title coordination polymer, [CuBr(C(3)H(5)N(3)S)](n), the Cu(I) atom adopts a tetra-hdral CuS(2)Br(2) coordination geometry arising from two S-bonded 4-methyl-1H-1,2,4-triazole-3 (4H)-thione ligands and two bromide ions. Both the S and Br atoms act as bridging ligands, connecting pairs of Cu(I) atoms and generating chains propagating in [100]. Inter-chain N-H ¦ N hydrogen bonds generate layers in the ac plane. Weak intra-chain N-HBr inter-actions also occur.Files
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Additional details
Additional titles
- Translated title (Arabic)
- - <i>سلسلة</i> بولي [نحاس(I) - ثنائي - μ - بروميدو - نحاس (I) - مكرر [μ -4 - methyl -1<i> H</i> -1,2,4 - triazole -5 (4<i>H</i>) - thione - κ<sup> 2</sup><i>S</i>:<i>S</i>]]
- Translated title (English)
- <i>-Poly chain</i> [copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1<i>H</i>-1,2,4-triazole-5(4<i>H</i>)-thione-κ<sup>2</sup><i>S</i>:<i>S</i>]]
- Translated title (French)
- <i>chaîne</i>-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1<i>H</i>-1,2,4-triazole-5(4<i>H</i>)-thione-κ<sup>2</sup><i>S</i> :<i>S</i>]]
- Translated title (Spanish)
- <i>cadena</i>-Poly[copper(I)-di-μ-bromido-copper(I)-bis[μ-4-methyl-1<i>H</i>-1,2,4-triazole-5(4<i>H</i>)-thione-κ<sup>2</sup><i>S</i>:<i>S</i>]]
Identifiers
- Other
- https://openalex.org/W2067532773
- DOI
- 10.1107/s1600536812014444
References
- https://openalex.org/W1979368277
- https://openalex.org/W1991347768
- https://openalex.org/W2012861603
- https://openalex.org/W2031158103
- https://openalex.org/W2039590858
- https://openalex.org/W2060724249
- https://openalex.org/W2131350133