Published March 23, 2011
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(Di-2-pyridylamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)[hydrotris(3,5-diphenylpyrazol-1-yl-κ<i>N</i><sup>2</sup>)borato]nickel(II) bromide dichloromethane monosolvate
- 1. Walailak University
- 2. University of Sheffield
Description
In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro-tris-(3,5-diphenyl-pyrazol-yl)borate ligand and a bidentate di-2-pyridyl-amine ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular N-H⋯Br and C-H⋯Br hydrogen bonds link the Ni complex cations and the Br(-) ions, forming a chain along the c axis.
Translated Descriptions
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This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
في مركب العنوان، [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2)، يتم تنسيق ذرة Ni(II) بواسطة ترايس هيدرو ترايدت- (3،5 -ثنائي فينيل- بيرازول- يل)بورات ليجند ورباط ثنائي- بيريديل- أمين ثنائي في هندسة هرمية مربعة مشوهة. في البلورة، تربط الروابط الهيدروجينية بين الجزيئات N - H Br و C - H Br الكاتيونات المعقدة Ni وأيونات Br (-)، وتشكل سلسلة على طول المحور c.Translated Description (English)
In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro-tris- (3,5-diphenyl-pyrazol-yl)borate ligand and a bidentate di-2-pyridyl-amine ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular N-H Br and C-H Br hydrogen bonds link the Ni complex cations and the Br(-) ions, forming a chain along the c axis.Translated Description (French)
In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro-tris- (3,5-diphenyl-pyrazol-yl)borate ligand and a bidentate di-2-pyridyl-amine ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular N-H- Br and C-H- Br hydrogen bonds link the Ni complex cations and the Br(-) ions, forming a chain along the c axis.Translated Description (Spanish)
In the title compound, [Ni(C(45)H(34)BN(6))(C(10)H(9)N(3))]Br·CH(2)Cl(2), the Ni(II) atom is five-coordinated by the tridentate hydro-tris- (3,5-diphenyl-pyrazol-yl) borate ligand and a bidentate di-2-pyridyl-amine ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular N-HBr and C-H Br hydrogen bonds link the Ni complex cations and the Br(-) ions, forming a chain along the c axis.Files
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Additional details
Additional titles
- Translated title (Arabic)
- (Di<sup> -2 - pyridylamine -</sup><i>κ</i> 2<i> N, N</i>′)[هيدروتريس (3,5 - diphenylpyrazol -1 - yl - κ<i> N</i><sup>2</sup>)بورات]نيكل(II) بروميد ثنائي كلورو ميثان أحادي الحل
- Translated title (English)
- (Di-2-pyridylamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)[hydrotris(3,5-diphenylpyrazol-1-yl-κ<i>N</i><sup>2</sup>)borate]nickel(II) bromide dichloromethane monosolvate
- Translated title (French)
- (Di-2-pyridylamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)[hydrotris(3,5-diphénylpyrazol-1-yl-κ<i>N</i><sup>2</sup>)borate]nickel(II) bromide dichlorométhane monosolate
- Translated title (Spanish)
- (Di-2-pyridylamine-κ<sup>2</sup><i>N</i>,<i>N</i>′)[hydrotris(3,5-diphenylpyrazol-1-yl-κ<i>N</i><sup>2</sup>)borato]níquel(II) bromide dichloromethane monosolvate
Identifiers
- Other
- https://openalex.org/W115085961
- DOI
- 10.1107/s1600536811010233
References
- https://openalex.org/W1983759499
- https://openalex.org/W1988325487
- https://openalex.org/W2009063511
- https://openalex.org/W2010557633
- https://openalex.org/W2031158103
- https://openalex.org/W2039089304
- https://openalex.org/W2043818479
- https://openalex.org/W2105249240
- https://openalex.org/W2131350133
- https://openalex.org/W2161370888
- https://openalex.org/W4239299913