Published September 29, 2012 | Version v1
Publication Open

4-Methoxy-<i>N</i>-(4-methoxy-2-nitrophenyl)benzamide

Creators

  • 1. International Center for Chemical and Biological Sciences
  • 2. University of Karachi

Description

In the title compound, C(15)H(14)N(2)O(5), the central amide C-C(=O)-N-C unit forms dihedral angles of 28.17 (13) and 26.47 (13)° with the two benzene rings, whereas the two benzene rings are almost coplanar, making a dihedral angle of 4.52 (13)°. The two meth-oxy and the nitro substituents are almost coplanar with their attached benzene rings, with C-O-C-C torsion angles of -1.3 (4) and -4.6 (4)°, and an O-N-C-C torsion angle of 17.1 (3)°. In the crystal, mol-ecules are linked via C-H⋯O and N-H⋯O inter-actions, forming a tape running along the b axis.

⚠️ This is an automatic machine translation with an accuracy of 90-95%

Translated Description (Arabic)

في مركب العنوان، C(15)H(14)N(2) O(5)، تشكل وحدة الأميد المركزي C - C(=O) - N - C زوايا ثنائية السطوح تبلغ 28.17 (13) و 26.47 (13) ° مع حلقتي البنزين، في حين أن حلقتي البنزين تكونان مستويتين تقريبًا، مما يجعل زاوية ثنائية السطوح 4.52 (13) °. إن بديلي الميثوكسي والنيترو عبارة عن نحاس تقريبًا مع حلقات البنزين المرفقة بهما، مع زوايا التواء C - O - C تبلغ -1.3 (4) و -4.6 (4) °، وزاوية التواء O - N - C تبلغ 17.1 (3) °. في البلورة، يتم توصيل جزيئات المول عبر C - H - O و N - H - O - التفاعلات، وتشكيل شريط يمتد على طول المحور b.

Translated Description (English)

In the title compound, C(15)H(14)N(2)O(5), the central amide C-C (=O) -N-C unit forms dihedral angles of 28.17 (13) and 26.47 (13) ° with the two benzene rings, whereas the two benzene rings are almost coplanar, making a dihedral angle of 4.52 (13) °. The two meth-oxy and the nitro substituents are almost copper with their attached benzene rings, with C-O-C torsion angles of -1.3 (4) and -4.6 (4) °, and an O-N-C-c torsion angle of 17.1 (3) °. In the crystal, mol-ecules are connected via C-H – O and N-H – O inter-actions, forming a tape running along the b-axis.

Translated Description (French)

Dans le composé du titre, C(15)H(14)N(2)O(5), l'unité amide centrale C-C (=O) -N-C forme des angles diédriques de 28,17 (13) et 26,47 (13) ° avec les deux cycles benzéniques, alors que les deux cycles benzéniques sont presque coplanaires, faisant un angle diédrique de 4,52 (13) °. Les deux substituants méthoxy et nitro sont presque en cuivre avec leurs cycles benzéniques attachés, avec des angles de torsion C-O-C de -1,3 (4) et -4,6 (4) °, et un angle de torsion O-N-C-c de 17,1 (3) °. Dans le cristal, les mol-écules sont connectées via des interactions C-H – O et N-H – O, formant un ruban longeant l'axe b.

Translated Description (Spanish)

En el compuesto del título, C(15)H(14)N(2)O(5), la unidad central de amida C-C (=O) -N-C forma ángulos diedros de 28,17 (13) y 26,47 (13) ° con los dos anillos de benceno, mientras que los dos anillos de benceno son casi coplanarios, formando un ángulo diedro de 4,52 (13) °. Los dos sustituyentes metoxi y nitro son casi de cobre con sus anillos de benceno unidos, con ángulos de torsión C-O-C de -1,3 (4) y -4,6 (4) °, y un ángulo de torsión O-N-C-c de 17,1 (3) °. En el cristal, las moléculas están conectadas a través de interacciones C-H-O y N-H-O, formando una cinta que se extiende a lo largo del eje b.

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Additional details

Additional titles

Translated title (Arabic)
4 -ميثوكسي- N<i> -(4</i> -ميثوكسي-2-نيترو فينيل)بنزاميد
Translated title (English)
4-Methoxy-N-<i> (</i>4-methoxy-2-nitrophenyl)benzamide
Translated title (French)
4-Méthoxy-N-<i> (</i>4-méthoxy-2-nitrophényl)benzamide
Translated title (Spanish)
4-Metoxi-N-<i> (</i>4-metoxi-2-nitrofenil)benzamida

Identifiers

Other
https://openalex.org/W1715764425
DOI
10.1107/s1600536812037701

Is supplement to
https://openalex.org/W2975885741 (Other)
https://openalex.org/W2917240981 (Other)
https://openalex.org/W2765156032 (Other)
https://openalex.org/W2526066714 (Other)
https://openalex.org/W2243424947 (Other)
https://openalex.org/W2230834018 (Other)
https://openalex.org/W2197172930 (Other)
https://openalex.org/W2173696553 (Other)
https://openalex.org/W1967544925 (Other)
https://openalex.org/W140016471 (Other)

GreSIS Basics Section

Is Global South Knowledge
Yes
Country
Pakistan

References

  • https://openalex.org/W1440307625
  • https://openalex.org/W1972493784
  • https://openalex.org/W2131350133
  • https://openalex.org/W2145538332
  • https://openalex.org/W317994616
  • https://openalex.org/W38285639