Published March 24, 2010
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Diazidobis(propane-1,3-diamine)copper(II)
- 1. Government College University, Lahore
- 2. Ondokuz Mayıs University
Description
In the title complex, [Cu(N(3))(2)(C(3)H(10)N(2))(2)], the Cu(II) ion resides on a centre of symmetry and is in a Jahn-Teller distorted octa-hedral coordination environment comprising two N atoms from azide anions in axial positions and four N atoms from propane-1,3-diamine (tn) ligands in equatorial positions. Inter-molecular N-H⋯N hydrogen bonds produce R(2) (1)(6), R(2) (2)(8), R(2) (2)(12) and R(4) (2)(8) rings, generating a two-dimensional layer.
Translated Descriptions
⚠️
This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
في مجمع العنوان، [Cu(N(3))(2)(C(3)H(10)N(2))(2)]، يقع أيون Cu(II) على مركز التناظر ويقع في بيئة تنسيق ثماني السطوح مشوهة Jahn - Teller تتألف من ذرتي N من الأنيونات الأزيدية في المواضع المحورية وأربع ذرات N من روابط البروبان-1,3 -ديامين (tn) في المواضع الاستوائية. تنتج الروابط الهيدروجينية N - H N بين الجزيئات حلقات R(2)(1) (6) و R (2)(2) (8) و R(2)(2)(12) و R(4) (2)(8)، مما يولد طبقة ثنائية الأبعاد.Translated Description (English)
In the title complex, [Cu(N(3))(2)(C(3)H(10)N(2))(2)], the Cu(II) ion resides on a center of symmetry and is in a Jahn-Teller distorted octa-hedral coordination environment comprising two N atoms from azide anions in axial positions and four N atoms from propane-1,3-diamine (tn) ligands in equatorial positions. Inter-molecular N-H N hydrogen bonds produce R(2) (1)(6), R(2) (2)(8), R(2) (2)(12) and R(4) (2)(8) rings, generating a two-dimensional layer.Translated Description (French)
In the title complex, [Cu(N(3))(2)(C(3)H(10)N(2))(2)], the Cu(II) ion resides on a centre of symmetry and is in a Jahn-Teller distorted octa-hedral coordination environment comprising two N atoms from azide anions in axial positions and four N atoms from propane-1,3-diamine (tn) ligands in equatorial positions. Inter-moléculaire N-H'N hydrogen bonds produit R(2) (1)(6), R(2) (2)(8), R(2) (2)(12) and R(4) (2)(8) rings, generating a two-dimensional layer.Translated Description (Spanish)
In the title complex, [Cu(N(3))(2)(C(3)H(10)N(2))(2)], the Cu(II) ion resides on a centre of simmetry and is in a Jahn-Teller distorted octa-hedral coordination environment comprising two N atoms from azide anions in axial positions and four N atoms from propane-1,3-diamine (tn) ligands in equatorial positions. Los bonos intermoleculares de hidrógeno N-H produce R(2) (1)(6), R(2) (2)(8), R(2) (2)(12) y R(4) (2) (8) rings, generando una capa de dos dimensiones.Files
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Additional details
Additional titles
- Translated title (Arabic)
- ديازيدوبيس(بروبان-1، 3 -ديامين)نحاس(II)
- Translated title (English)
- Diazidobis(propane-1,3-diamine)copper(II)
- Translated title (French)
- Diazidobis(propane-1,3-diamine)cuivre(II)
- Translated title (Spanish)
- Diazidobis(propano-1,3-diamina)copper(II)
Identifiers
- Other
- https://openalex.org/W2231827250
- DOI
- 10.1107/s1600536810010184
References
- https://openalex.org/W1970118204
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