Published March 26, 2014
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Bis(2-methoxybenzylammonium) diaquabis(dihydrogen diphosphato-κ<sup>2</sup><i>O</i>,<i>O</i>′)cobaltate(II) dihydrate
- 1. Centre d'Élaboration de Matériaux et d'Études Structurales
- 2. French National Centre for Scientific Research
Description
The title compound, (C 8 H 12 NO) 2 [Co(H 2 P 2 O 7 ) 2 (H 2 O) 2 ]·2H 2 O, crystallizes isotypically with its Mn II analogue. It consists of alternating layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co 2+ atom has an octahedral coordination sphere, defined by two water molecules in apical positions and two H 2 P 2 O 7 2− ligands in equatorial positions. The cohesion between inorganic and organic layers is accomplished by a set of O—H...O and N—H...O hydrogen bonds involving the organic cation, the inorganic anion and the remaining lattice water molecules.
Translated Descriptions
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This is an automatic machine translation with an accuracy of 90-95%
Translated Description (Arabic)
يتبلور مركب العنوان، (C 8 H 12 NO) 2 [Co(H 2 P 2 O 7 ) 2 (H 2 O) 2 ] 2 H 2 O بشكل متماثل مع نظيره Mn II. وهو يتألف من طبقات متناوبة من الكاتيونات العضوية والأنيونات المعقدة غير العضوية، وتمتد بالتوازي مع (100). يظهر أنيون الكوبالتات المعقد (II) -1 تماثل. تحتوي ذرة ثاني أكسيد الكربون الخاصة بها على كرة تنسيق ثماني السطوح، محددة بجزيئي ماء في مواضع قمية وربيطتين H 2 P 2 O 7 2 في مواضع استوائية. يتم تحقيق التماسك بين الطبقات غير العضوية والعضوية من خلال مجموعة من روابط الهيدروجين O - H...O و N - H... O التي تتضمن الكاتيون العضوي والأنيون غير العضوي وجزيئات الماء اللاتكس المتبقية.Translated Description (English)
The title compound, (C 8 H 12 NO) 2 [Co(H 2 P 2 O 7 ) 2 (H 2 O) 2 ]·2H 2 O, crystallizes isotypically with its Mn II analogue. It consists of alternating layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co 2+ atom has an octahedral coordination sphere, defined by two water molecules in apical positions and two H 2 P 2 O 7 2− ligands in equatorial positions. The cohesion between inorganic and organic layers is accomplished by a set of O—H...O and N—H...O hydrogen bonds involving the organic cation, the inorganic anion and the remaining latex water molecules.Translated Description (French)
The title compound, (C 8 H 12 NO) 2 [Co(H 2 P 2 O 7 ) 2 (H 2 O) 2 ]·2H 2 O, crystallizes isotypically with its Mn II analogue. It consists of alterning layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co 2+ atom has an octahedral coordination sphere, defined by two water molecules in apical positions and two H 2 P 2 O 7 2− ligands in equatorial positions. The cohesion between inorganic and organic layers is accomplished by a set of O—H...O and N—H...O hydrogen bonds involving the organic cation, the inorganic anion and the remaining lattice water molecules.Translated Description (Spanish)
The title compound, (C 8 H 12 NO) 2 [Co(H 2 P 2 O 7 ) 2 (H 2 O) 2 ]·2H 2 O, crystallizes isotypically with its Mn II analogue. It consists of alternating layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co 2+ atom has an octahedral coordination sphere, defined by two water molecules in apical positions and two H 2 P 2 O 7 2− ligands in equatorial positions. The cohesion between inorganic and organic layers is accomplished by a set of O—H...O and N—H...O hydrogen bonds involving the organic cation, the inorganic anion and the remaining látex water molecules.Files
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Additional details
Additional titles
- Translated title (Arabic)
- ثنائي(2 -ميثوكسي بنزيلامونيوم) ثنائي(ثنائي هيدروجين ثنائي فوسفات - κ<sup> 2</sup><i>O</i>,<i>O</i>')ثنائي هيدرات الكوبالتات (II)
- Translated title (English)
- Bis(2-methoxybenzylammonium) diquabis(dihydrogen diphosphate-κ<sup>2</sup><i>O</i>,<i>O</i>′)cobaltate(II) dihydrate
- Translated title (French)
- Bis(2-méthoxybenzylammonium) diaquabis(dihydrogen diphosphato-κ<sup>2</sup><i>O</i>,<i>O</i>′)cobaltate(II) dihydrate
- Translated title (Spanish)
- Bis(2-methoxybenzylammonium) diaquabis(dihydrogen diphosphato-κ<sup>2</sup><i>O</i>,<i>O</i>′)cobaltate(II) dihydrate
Identifiers
- Other
- https://openalex.org/W2603427890
- DOI
- 10.1107/s1600536814006102
References
- https://openalex.org/W56763115
- https://openalex.org/W263922080
- https://openalex.org/W338719814
- https://openalex.org/W1820978109
- https://openalex.org/W1970522609
- https://openalex.org/W1980070399
- https://openalex.org/W1990170643
- https://openalex.org/W2072562804
- https://openalex.org/W2131350133
- https://openalex.org/W2147895593
- https://openalex.org/W2158410628
- https://openalex.org/W2158827289
- https://openalex.org/W2614459658